| Common name: bromoxynil |
U.S. trade name: BUCTRIL |
Bromoxynil [post-emergent (POST)]
on redroot pigweed (Amaranthus retroflexus).
Note the mottling and numerous necrotic spotting

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Bromoxynil (POST) on soybean

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Bromoxynil (POST) on common
lambsquarters (Chenopodium album)

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Bromoxynil (POST) on broadleaf weeds

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Bromoxymil (POST) on broadleaf
and grass crops and weeds

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Chemical Name:
3,5-dibromo-4-hydroxybenzonitrile.
Chemical Family:
Nitriles (or Benzonitriles).
Chemical Structure:
WSSA resistance group:
6.
Crop/non-crop registration:
Field corn, wheat, oats, barley, rye, triticale, seedling alfalfa, flax, turfgrasses for sod or seed, garlic.
Sensitive weeds:
Many annual BLW (broadleaf weeds): wild buckwheat, smartweed, lamb's-quarters, wild mustard kochia, cocklebur, velvetleaf, nightshades (but most effective before 5-leaf stage)
Application method: POST.
Absorption & Translocation:
Absorbed by foliage and moves very little within the plant.
Mode of action:
Inhibition of photosynthesis and ATP formation by blocking electron transport.
Metabolic pathway inhibited:
Inhibition of photosynthesis by binding to the QB-binding niche on the D1 protein of the photosystem II complex in chloroplast thylakoid membranes, thus blocking electron transport from QA to QB;this stops CO2 fixation and production of ATP and NADPH2 which are required for plant growth; however, plant death often results from other factors (e.g. lipid peroxidation).
Basis of selectivity:
Differential spray retention, uptake and degradation in tolerant species.
Symptoms:
Basically a foliar contact herbicide; causes blistered (mottling) or necrotic spots within 24 hours and extensive destruction of leaf tissue later (4-7 days); chlorosis may appear afterwards around the necrotic areas of leaves; susceptible seedlings become extremely brittle and eventually disintegrate.
Residuality:
Essentially none; short (< 1month).
Toxicity:
Oral LD
50 = 440 mg/kg - very toxic (BUCTRIL = 779 mg/kg - moderately toxic).
Additional comments:
Formulation includes a wetting agent to improve the spread of droplets on leaf; although bromoxynil is not an effective soil-applied herbicide, crops such as turnips, peas and beans should not be seeded for 1-week following application; crop injury (leaf scorch) may develop if plant is under stress (high temperatures or high humidity) within 2 or 3 days before or after application; in corn, problems arise if application followed by a period of cool, wet weather, however, yields are generally not affected.